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paiN Gaming is a Brazilian eSports organization that was established in 2010. Then the organization did not have its own DotA 2 team. But it was decided, in connection with the popularization of the game, to unite the two teams that performed in the DotA All-stars discipline. After the merger of the two GameWise and CNB teams, with players such as «Dunnaz», «r22», «Elai», «PAADA», «KINGRD», «Sune», «GrentxD», the organization introduced its paiN Gaming team in DotA 2.
Then the team led by Arthur «PAADA» Zarzur and having such a sponsor as «Razor» achieved excellent results. The team showed quite a good game with such players as «PAADA», «KINGRD», «Sune», «ChiNa», «GrentxD» and «Markeka».But the organization was not satisfied with the results of the team, and it was decided to dissolve the composition. Soon a new team was assembled, which included players from Argentina, such as: «ddx», «Zurdo», «Ektoplazm», «Fullback», and «Gengar».But with the new roster, the team was also unable to achieve the expected results, as the team did not even go through the qualifying round at The International 2015. Therefore, they decided to change the roster again. «Vestius», «KINGRD» and «Baga» left the team and were replaced by «hFnk3», «July» and «c4t». After which the team successfully won first place at the Brasil Game Show 2015. In 2016, after a series of defeats, the organization announced that the paiN Gaming Dota 2 team would be dissolved. It was the decision of the players themselves, who decided to leave the club and play under a different name.
In the fall of 2017, the organization announced its return, bringing together a new roster, «hFn», «Mandy», «Tavo», «KINGRD» and «Duster». With this roster, the team was able to take first place at the WESG 2017 South America Finals tournament and second place at World Electronic Sports Games 2017. But even with a good team and a good enough season, the team dropped out one of the first at The International 2018, taking 17-18th place.
On January 15, 2019, the roster was signed by Chaos Esports Club. And the team with «hFn», «tavo», «w33», «Kingrd», «MiSeRy» switched to another organization. Then paiN Gaming decided not to collect a new roster and signed the Butterfly Effect team, namely «hFn», «4dr», «Lelis», «Thiolicor» and «444». But the new team did not show even close the results of the previous roster, so the organization decided to disband the roster in April 2020. The team's best result was third place at CBDota 2 in March 2020.
As of December 2020, the organization does not have a Dota 2 roster.